Directed nucleation of monomeric and dimeric uranium(VI) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid.

نویسندگان

  • Xiao-Yan Chen
  • George S Goff
  • Mauricio Quiroz-Guzman
  • Daniel P Fagnant
  • Joan F Brennecke
  • Brian L Scott
  • Wolfgang Runde
چکیده

The carboxyl-functionalized phosphonium ionic liquid (IL), [HCTMP][Tf(2)N], enabled the directed nucleation of monomeric or dimeric uranyl(vi) compounds. This new IL is the first carboxyl-functionalized IL which is liquid at room temperature and exhibits a wider electrochemical window and lower melting point than its ammonium analogue.

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عنوان ژورنال:
  • Chemical communications

دوره 49 19  شماره 

صفحات  -

تاریخ انتشار 2013